The meterological and photochemical nature of the South Atlantic Ocean tropospheric column ozone maximum is examined by analyzing the Geophysical Fluid Dynamics Laboratory (GFDL) Global Chemical Transport Model (GCTM) simulation during the Southern Hemisphere late winter. An ozone maximum of greater than 40 Dobson units is produced by the GCTM over the South Atlantic Ocean. The model is evaluated against available meteorological and ozone data and found to be in good qualitative agreement with observed wind fields, satellite measurements of tropospheric column ozone, tropospheric column ozone produced from ozonesonde data, and vertical profiles from ozonesondes. A quantitative analysis is performed over an area of the South Atlantic Ocean essentially devoid of local NOx sources and for a time, September, when the regional tropospheric ozone mass is at a maximum. The tropospheric mass of reactive nitrogen transported into the region is a result of source contributions from lightning (49%), biomass burning (36%), and 15% from the remaining NOx sources (fossil fuel plus biogenic plus stratosphere plus aircraft). Even with the removal of biomass burning NOx from the ozone photochemical system, the GCTM still produces an oceanic tropospheric column ozone maximum, suggesting the ozone phenomenon existed before agricultural burning by humans. The structure of clean air CO/CH4 net chemistry consists of ozone production in the upper troposphere (+2.2 Tg/month), weak destruction in the middle troposphere (- 1.8 Tg/month), and strong destruction in the lower troposphere (- 4.2 Tg/month). Through photochemistry, the two largest NOx sources help control the vertical profile of ozone with lightning dominating in the upper troposphere, while the relative importance of biomass burning is virtually constant throughout the troposphere. A mass budget analysis of ozone over the tropospheric South Atlantic Ocean reveals that net mass transport of ozone into the domain is nearly balanced by net chemical destruction and deposition and that the mass transport into and out of the region are comparable to the chemical production and destruction terms. The three-dimensional circulation governing the ozone vertical structure is one of horizontal mass convergence and net chemical production supplying ozone to the upper troposphere which is fluxed downward by subsidence and removed in the boundary layer by net chemical destruction, deposition, and horizontal mass divergence. ¿ 2000 American Geophysical Union