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Saxon & Slanger 1986
Saxon, R.P. and Slanger, T.G. (1986). Molecular oxygen absorption continua at 195-300 nm and O2 radiative lifetimes. Journal of Geophysical Research 91: doi: 10.1029/JD091iD09p09877. issn: 0148-0227.

With the aid of new calculations on the transition moments between the six lowest states of O2, absorption cross sections have been calculated for several oxygen continua, including the &Agr;2u+← &KHgr;3g- and &Agr;'3Δua1Δg systems. Reasonable agreement is achieved with recent experimental results, the comparison indicating an overestimation ofthe theoretical transition moment for the &Agr;-&KHgr; system of 20--25%. With this adjustment, the calculated radiative lifetime for the O2(&Agr;) state is 150 ms, in close agreement with the currently used value. The &Agr;'a and &Agr;←&KHgr; continua cross sections are of similar magnitude, indicating that absorption by O2(a) can not be a significant atmospheric process.

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Abstract

Journal
Journal of Geophysical Research
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American Geophysical Union
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