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Kostiuk et al. 1986
Kostiuk, T., Faris, J.L., Mumma, M.J., Deming, D. and Hillman, J.J. (1986). Infrared line intensities of chlorine monoxide. Journal of Geophysical Research 91: doi: 10.1029/JD091iD02p02735. issn: 0148-0227.

Absolute infrared line intensities of several ClO lines in the rotational-vibrational (1-0) band were measured using infrared heterodyne spectroscopy near 12 μm. A measurement technique using combined ultraviolet absorption and infrared line measurements near 9.5 μm and 12 μm permitted an accurate determination of the column densities of O3 and ClO in the absorption cell and thus improved ClO line intensities. Results indicate ClO line and band intensities ~2.4 times lower than previous experimental results. Effects of possible failure of local thermodynamic equilibrium conditions in the absorption cell and the implication of the results of stratospheric ClO measurements in the infrared are discussed.

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Journal of Geophysical Research
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American Geophysical Union
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