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Detailed Reference Information |
Davidson, J.A., Cantrell, C.A., McDaniel, A.H., Shetter, R.E., Madronich, S. and Calvert, J.G. (1988). Visible-Ultraviolet absorption cross sections for NO2 as a function of temperature. Journal of Geophysical Research 93: doi: 10.1029/88JD01676. issn: 0148-0227. |
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A redetermination of the temperature dependence of the absorption cross section (&sgr;) for NO2 in the visible-ultraviolet region (264--649 nm) has been made in order to provide a more reliable data base for the calculation of NO2 photolysis rates in the atmosphere. Experiments over a wide range of temperatures (-40.6¿ to 124¿C) and NO2 concentrations (3.4¿1013-7.3¿1014 molecules cm-3) were made at relatively low and high spectral resolutions, employing diode array and Fourier transform spectrometers, respectively. There are three aspects of the temperature dependence which were noted: (1) the integral of a plot of &sgr; versus 1/λ&sgr; (264-649 nm) was essentially independent of temperature; (2) increasing temperature produced a shift of the spectrum toward longer wavelengths, in a small negative temperature dependence of &sgr; over the 264-- to 400-nm range and a small positive dependence over the 450-- to 649-nm range; (3) increasing temperature produced broadening of individual spectral features, resulting in a systematic lowering of peaks and filling of valleys. Recommended cross sections, averaged over 5-nm wavelength intervals, are presented for use in tropospheric NO2, photolysis rate calculations. ¿ American Geophysical Union 1988 |
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BACKGROUND DATA FILES |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Transmission and scattering of radiation, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Pollution—urban and regional |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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