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Detailed Reference Information |
Ballard, J., Johnston, W.B., Gunson, M.R. and Wassell, P.T. (1988). Absolute absorption coefficients of ClONO2 infrared bands at stratospheric temperatures. Journal of Geophysical Research 93: doi: 10.1029/88JD01598. issn: 0148-0227. |
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Fourier-transform absorption spectroscopy has been used in the laboratory to obtain absolute absorption coefficients &sgr;(&ngr;) in infrared bands of ClONO2 in the 700--1800 cm-1 spectral region. These data have been obtained over a temperature range (213--296 K) corresponding to stratospheric temperatures. The results are therefore applicable to retrievals of stratospheric ClONO2 from remote-sensing observations. Room temperature absorption coefficients are some 25% larger than previously reported values, and large temperature dependences in the absorption coefficients have been observed. The &ngr;1 and &ngr;2 bands behave as simple fundamentals of a system which has low-energy vibrational or torsional modes, with little contribution from hot bands over the temperature range used. The intensity in the &ngr;2 Q branch increased by 53% over the temperature range 296--213 K. A similar increase was observed for the &ngr;4 Q branch, and significant hot-band features were seen in the &ngr;3, &ngr;4 spectral region. The &ngr;4Q branch and the &ngr;2 Q branch were observed to obey the Beer Lambert law over the range of pressure, temperature, absorber, amount, and resolution employed. The absorption coefficients in the &ngr;4 Q branch and in the &ngr;2 band were modeled by equispaced absorption lines, each characterized by a central freuqency, strength, lower-state energy, and pressure-broadened width. ¿ American Geophysical Union 1988 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Transmission and scattering of radiation, Atmospheric Composition and Structure, Instruments and techniques |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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