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De Zafra et al. 1989
De Zafra, R.L., Jaramillo, M., Barrett, J., Emmons, L.K., Emmons, L.K., Solomon, P.M. and Parrish, A. (1989). New observations of a large concentration of ClO in the Springtime lower stratosphere over Antarctica and its implications for ozone-depleting chemistry. Journal of Geophysical Research 94: doi: 10.1029/89JD00852. issn: 0148-0227.

We have made new measurements of stratospheric chlorine monoxide (ClO) at McMurdo Station, Antarctica, during the austral spring of 1987. Rotational emission line spectroscopy, employing a ground-based detector, was used to determine mixing ratio profiles over the range ~17--45 km. A spectral band pass double that was used for similar measurements in 1986 allowed an improvement to be made in the definition of the anomalous low-altitude stratospheric ClO layer associated with springtime ozone depletion. A peak minimum ratio of 1.6¿0.4 parts per billion by volume (ppbv) (95% confidence level) was found at 19.5¿1 km at midday during the period September 20--24, 1987. The observed peak mixing ratio and diurnal behavior are discussed in relation to chemical depletion theories. Calculations indicate that the large observed ClO concentration provides an efficient closure for a catalytic Cl cycle through the ClO dimer mechanism, yielding good agreement with various observed features of O3 depletion. ¿ American Geophysical Union 1989

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Information Related to Geographic Region, Antarctica
Journal
Journal of Geophysical Research
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Publisher
American Geophysical Union
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