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Jacob et al. 1989
Jacob, D.J., Sillman, S., Logan, J.A. and Wofsy, S.C. (1989). Least independent variables method for simulation of tropospheric ozone. Journal of Geophysical Research 94: doi: 10.1029/89JD00308. issn: 0148-0227.

We describe a method for simulating photochemical production of O3 in a continental-scale tropospheric model with only six independent chemical variables representing tracers transported in the model. The tracers are two primary hydrocarbon families, CO, NOx, peroxyacylinitrates, and odd oxygen (Ox). A chemical module is developed to compute the production and loss rates of tracers over a model time step of 4 hours, using only information on the tracer concentrations input to the module at the beginning of the time step. Test simulations for summertime conditions at mid-latitudes indicate little loss in accuracy compared to detailed model simulations of chemistry with high time resolution. Minimization of the number of tracers and use of a long time step reduces computer time and storage requirements. In addition, parameterization of the chemical computation is facilitated, allowing further savings in computer time. ¿ American Geophysical Union 1989

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Abstract

Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Pollution—urban and regional, Atmospheric Composition and Structure, Instruments and techniques
Journal
Journal of Geophysical Research
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Publisher
American Geophysical Union
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