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Tyler et al. 1990
Tyler, S.C., Lowe, D.C., Dlugokencky, E., Zimmerman, P.R. and Cicerone, R.J. (1990). Methane and carbon monoxide emissions from asphalt pavement: Measurements and estimates of their importance to global budgets. Journal of Geophysical Research 95: doi: 10.1029/90JD00408. issn: 0148-0227.

We measured emissions of methane from asphalt surfaces used in pavement for roadways. Maximum emissions were 22 mg/m2/hr for 1- to 4-week-old pavement during maximum sunlight intensity. Emissions were much smaller at low sunlight intensity and dropped off to negligible amounts at night. Smaller emissions were observed for asphalt pavement of 2.5 to 3 years approximate age under similar conditions. Companion measurements of carbon monoxide emissions resulted in maximum emissions of about 2.6 mg/m2/hr for 1-week-old pavement. These findings indicate that emissions of CH4 and CO are a function of both sunlight and temperature. Based on our results methane emissions from asphalt pavement cannot be a significant source of atmospheric methane as compared to other identified methane sources. Therefore, although asphalt methane emissions are a form of fossil fuel methane, they cannot explain the relatively high fraction of 14C-depleted methane in the atmosphere. ¿American Geophysical Union 1990

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