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Johnson & Kumar 1991
Johnson, S.A. and Kumar, R. (1991). Composition and spectral characteristics of ambient aerosol at Mauna Loa Observatory. Journal of Geophysical Research 96: doi: 10.1029/89JD03560. issn: 0148-0227.

Ambient aerosol particle were sampled continuously with a time resolution of ~4 hours for a period of 8 days at the Mauna Loa Observatory, Hawaii, in August 1986. The samples were analyzed on-site for their chemical composition by attenuated total internal reflection infrared spectroscopy. The infrared absorption spectra of the samples also provided data on aerosol light absorbance characteristics at 9.1 and 10.6 μm-wavelengths of interest in determining aerosol backscatter coefficients for CO2 lidars. The chemical species in the ambient aerosol varied considerably during this 8-day period. The aerosol was acidic <(NH4)3H(SO4)2, NH4HSO4, or H2SO4> rather than neutral <(NH4)2SO4> for a major fraction of the sampling time. The samples generally showed much higher absorbance 9.1 μm than at 10.6 μm. Changes in the chemical composition between (NH4)2SO4 and the more acidic forms were accompanied by substantial changes in the sample's absorbance at 9.1 μm but lesser changes in the absorbance at 10.6 μm. These variations could have a profound effect on backscatter coefficients of atmospheric aerosol particles at CO2 wavelengths. ¿American Geophysical Union 1991

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Keywords
Atmospheric Composition and Structure, Instruments and techniques, Atmospheric Composition and Structure, Aerosols and particles, Atmospheric Composition and Structure, Pollution—urban and regional, Atmospheric Composition and Structure, Troposphere—composition and chemistry
Journal
Journal of Geophysical Research
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Publisher
American Geophysical Union
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