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Sandholm et al. 1992
Sandholm, S.T., Bradshaw, J.D., Chen, G., Singh, H.B., Talbot, R.W., Gregory, G.L., Blake, D.R., Sachse, G.W., Browell, E.V., Barrick, J.D.W., Shipham, M.A., Bachmeier, A.S. and Owen, D. (1992). Summertime tropospheric observations related to Nx Oy distributions and partitioning over Alaska: Arctic Boundary Layer Expedition 3A. Journal of Geophysical Research 97: doi: 10.1029/92JD01491. issn: 0148-0227.

Measurements of the reactive odd nitrogen cmpounds NO, NO2, peroxyacetyl nitrage (PAN), and NOy are presented for the summertime middle/lower troposphere (6.1--0.15 km) over northern high latitudes. In addition, the chemical signatures revealed from concurrent measurements of O3, CO, C2H2, C2H6, C3H8, C2Cl4, and H2O are used to further characterize factors affecting the budget and distribution of NxOy in the Arctic and sub-Arctic tropospheric air masses sampled over Alaska during the NASA Arctic Boundary Layer Expedition (ABLE 3A) field campaign. Many of the compounds listed above exhibited a general trend of median mixing ratios increasing in proportion with altitude within the lower 6 km column. However, median mixing ratios of NO and NOx (NO+NO2) were nearly independent of altitude, having values of about 8.5 and 25 pptv, respectively. Median mixing ratios of NOy varied from 350 pptv within the lowest altitudes to about 600 pptv within the highest altitudes sampled. PAN constituted the largest fraction of NOy (~50%) at the highest altitudes. In addition, PAN mixing accounted for all of the approximate 60 pptv/km altitudinal dependency in NOy. The analyses presented implicate biomass burning in Siberia as the probable source of about one-third of the NOy abundance within the middle/lower troposphere over Alaska. These analyses also implicate the downward transport of air from altitudes in the vicinity of tropopause as a major contributor to the abundance of NOy (~30--50%) within the lower 6-km column over Alaska. However, the exact origin of this high-altitude NOy remains uncertain. The impact of lower latitude industrial/urban pollution also remains largely uncertain, although various chemical signatures imply inputs from these regions would have been relatively well aged (15--30 days). ¿ American Geophysical Union 1992

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Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Biosphere-atmosphere interactions
Journal
Journal of Geophysical Research
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American Geophysical Union
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