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Burkholder 1993
Burkholder, J.B. (1993). Ultraviolet absorption spectrum of HOCl. Journal of Geophysical Research 98: doi: 10.1029/92JD02522. issn: 0148-0227.

The room temperature UV absorption spectrum of HOCl was measured over the wavelength range 200 to 380 nm with a diode array spectrometer. The absorption spectrum was identified from UV absorption spectra recorded following UV photolysis of equilibrium mixtures of Cl2O/H2O/HOCl. The HOCl spectrum is continuous with a maximum at 242 nm and a secondary peak at 304 nm. The measured absorption cross section at 242 nm was (2.1¿0.3)¿10-19 cm2 (2 &sgr; error limits). These results are in excellent agreement with the work of Knauth et al. (1979) but in poor agreement with the more recent measurement of Mishalanie et al. (1986) and Permien et al. (1988). An HOCl &ngr;2 infrared band intensity of 230¿35 cm-2 atm-1 was determined based on this UV absorption cross section. The present results are compared with these previous measurements and the discrepancies are discussed. ¿American Geophysical Union 1993

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Keywords
Atmospheric Composition and Structure, Transmission and scattering of radiation, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Troposphere—composition and chemistry
Journal
Journal of Geophysical Research
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American Geophysical Union
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