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Detailed Reference Information |
Montierth, K.V., Baker, K.D., Jensen, L.L. and Megill, L.R. (1993). Determination of molecular dissociation rates from measurements of scattered solar ultraviolet light. Journal of Geophysical Research 98: doi: 10.1029/93JD00254. issn: 0148-0227. |
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Scattered solar ultraviolet light in the spectral region from 250 to 320 nm was measured from a balloon platform at altitudes ranging from 14.5 to 38.8 km with a wavelength resolution of approximately 0.3 nm and an accuracy in determining the wavelength position of 0.5 nm. We used these scatter data to compare and validate a single scattering model developed for this purpose. Using these semi-empirical results, we constructed the single scattered component of the ultraviolet irradiance as a function of height and wavelength. From these data, it is possible to determine the percentage dissociation rate of a variety of species due to scattered ultraviolet radiation. These results are presented as a ratio of intensities R=I1/(I0+I1), where I1 is the first order scattering and I0 is the direct attenuated radiation from the sun. The attenuated direct radiation from the sun can be multiplied by the factor 1/(1-R), the Rayleigh amplification ratio used by Nicolet et al. (1982), to include the contribution to the irradiance from first order scattered light. The results are multiplied by a cross section of the species under consideration to obtain the dissociation rates. Ozone overburden and an approximate ozone particle density altitude profile are obtained when validating the single scatter model. ¿ American Geophysical Union 1993 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Meteorology and Atmospheric Dynamics, Convective processes, Meteorology and Atmospheric Dynamics, Tropical meteorology |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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