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Rinsland et al. 1993
Rinsland, C.P., Gunson, M.R., Abrams, M.C., Lowes, L.L., Zander, R. and Mahieu, E. (1993). ATMOS/ATLAS 1 measurements of sulfur hexafluoride (SF6) in the lower stratosphere and upper troposphere. Journal of Geophysical Research 98: doi: 10.1029/93JD02258. issn: 0148-0227.

Vertical profiles of sulfur hexafluoride (SF6) in the lower stratosphere and upper troposphere have been retrieved from 0.01-cm-1 resolution infrared solar occultation spectra recorded by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier transform spectrometer during the ATLAS (Atmospheric Laboratory for Applications and Science) 1 shuttle mission of March 24 to April 2, 1992. Based on measurements of the unresolved absorption by the SF6 &ngr;3 band Q branch at 947.9 cm-1, average SF6 volume mixing ratios and 1-sigma uncertainties of 3.20¿0.54 parts per trillion by volume (pptv; 10-12 ppv) at 200 mbar (~11.8 km) declining to 2.86¿0.29 pptv at 100 mbar (~16.2 km) and 1.95¿0.50 pptv at 30 mbar (~23.9 km) have been retrieved. The profiles show no obvious dependence with latitude over the range of the measurements (eight occultations spanning 28¿S to 54¿S). Assuming an exponential growth model and applying a correction for the interhemispheric concentration difference, an average SF6 rate of increase of 8.7¿2.2% per year, 2 sigma, between 12 and 18 km has been derived by fitting the present measurements. ATMOS measurements from the April-May 1985 Spacelab 3 mission, and balloon-borne IR measurements obtained in March 1981 and June 1988. ¿ American Geophysical Union 1993

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Keywords
Atmospheric Composition and Structure, Evolution of the atmosphere, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Transmission and scattering of radiation, Atmospheric Composition and Structure, Aerosols and particles
Journal
Journal of Geophysical Research
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American Geophysical Union
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