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Rinsland et al. 1994
Rinsland, C.P., Jones, N.B. and Matthews, W.A. (1994). Infrared spectroscopic measurements of the total column abundance of ethane (C2H6) above Lauder, New Zealand. Journal of Geophysical Research 99: doi: 10.1029/94JD02386. issn: 0148-0227.

Total vertical column abundances of atmospheric ethane (C2H6) have been retrieved from more than 350 high-resolution infrared solar spectra recorded on 129 days between December 1992 and March 1994 at the Network for the Detection of Stratospheric Change (NDSC) station in Lauder, New Zealand (latitude 45.04¿S, 169.68¿E, 0.37 km altitude). The results are based on nonlinear least squares fits to narrow spectral intervals containing the unresolved C2H6 &ngr;7 band PQ3 and RQ0 subbranches at 2976.8 and 2986.7 cm-1, respectively. The measured Lauder column abundances show a pronounced seasonal cycle with a maximum value of (8.6¿1.1)¿1015 molecules cm-2 in September and a minimum value of (3.8¿0.5)¿1015 molecules cm-2 in February.

Assuming a realistic vertical distribution for C2H6, these values correspond to surface level volume-mixing ratios of 0.52 and 0.23 ppbv (parts per billon by volume) respectively. The phase and relative amplitude of the Lauder C2H6 seasonal cycle are similar to corresponding values determined from infrared measurements at the Jungfraujoch (46.55¿N, 7.98¿E, 3.58 km altitude) and Mauna Loa (latitude 19.5¿N, longitude 155.6¿W, 3.5 km altitude), NDSC stations, but the inferred absolute magnitude of the Lauder surface level mixing ratios during the same season are significantly lower. The Lauder C2H6 measurements are also compared with published southern hemisphere surface level sampling measurements and two-dimensional model calculations. ¿American Geophysical Union 1994

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Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Pollution—urban and regional, Atmospheric Composition and Structure, Transmission and scattering of radiation
Journal
Journal of Geophysical Research
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American Geophysical Union
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