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Detailed Reference Information |
Tuck, A.F., Fahey, D.W., Loewenstein, M., Podolske, J.R., Kelly, K.K., Hovde, S.J., Murphy, D.M. and Elkins, J.W. (1994). Spread of denitrification from 1987 Antarctic and 1988–1989 Arctic stratospheric vortices. Journal of Geophysical Research 99: doi: 10.1029/94JD01532. issn: 0148-0227. |
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Vertical profiles of N2O and NOy taken by the ER-2 outside the vortex are used to construct average vertical profiles of F(NOy)=NOy/(A-N2O), where A is the tropospheric content of N2O three years prior to the measurements. The southern hemisphere had less nitrous oxide in the range 400≤&thgr;≤470 K, by up to 25% relative to the northern hemisphere. F(NOy) is the ratio of NOy produced to N2O lost in a stratospheric air mass since entry from the troposphere. The profiles of F(NOy) have the following characteristics: (1) Relative to 1991--1992, a year without denitrification inside or outside the vortex ranging up to 25% and averaging 17% above &thgr;=425 K. (2) Relative to the northern hemisphere in 1991--1992, the southern hemisphere in 1987 showed denitrification outside the vortex ranging up to 32% and averaging 20% above &thgr;=400 K. (3) Below &thgr;=400 K the southern hemisphere showed enhancements of F(NOy) relative to the northern hemisphere in 1991--1992 ranging up to 200% at &thgr;=375 K, outside the vortex. Corresponding profiles of residual water, R(H2O)=H2O-2<1⋅6-CH4>, are considered and shown to be consistent with those of F(NOy) in the sense that they show deficits outside the Antarctic vortex, which was both dehydrated and denitrified, but not outside the 1988--1989 Arctic vortex, which was denitrified but not dehydrated. R(H2O) is the water content of stratospheric air with the contribution from methane oxidation subtracted. Comparison of F(NOy) and R(H2O) below 400 K outside the Antarctic vortex leads to the suggestion that dehydration in the Antarctic vortex occurs by the sedimentation of ice crystals large enough to fall out of the stratosphere, whereas denitrification occurs mainly on mixed nitric acid-water crystals which evaporate below the base of the vortex at &thgr;=400 K but above the tropopause. ¿ American Geophysical Union 1994 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Meteorology and Atmospheric Dynamics, Middle atmosphere dynamics, Meteorology and Atmospheric Dynamics, Polar meteorology |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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