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Miyamoto et al. 1993
Miyamoto, M., Furuta, T., Fujii, N., McKay, D.S., Lofgren, G.E. and Duke, M.B. (1993). The Mn-Fe negative correlation in olivines in ALPHA 77257 ureilite. Journal of Geophysical Research 98: doi: 10.1029/92JE02943. issn: 0148-0227.

Mn, Fe, and oxygen zoning profiles of olivines in the ALHA 77257 ureilite were measured by an electron probe microanalyzer to study the effects of reduction on the Mn-Fe value, because ureilite olivines exhibit thin reduced rims. The Mn content gradually increases toward the rim of ureilite olivines as the Fa (=100¿Fe/(Mg+Fe), mol %) component decreases, which suggests that the Mn-Fe content of olivine is related to redox conditions. A calculated diffusional cooling rate of 1--2 ¿C/h gives the best fit to both the observed MnO and Fa chemical zoning profiles of ALHA 77257. The results of melting experiments suggest that the negative correlation of Mn-Fe in olivine and low-Ca pyroxene is related to reduction and that the Mn-Fe positive correlation is related to temperature. The Fe/Mn-Fe/Mg trend of olivine cores in ureilites may be established by the reduction process at about 1275 ¿C. ¿ American Geophysical Union 1993

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Abstract

Keywords
Geochemistry, Chemical evolution, Mineralogy and Petrology, Experimental mineralogy and petrology, Mineralogy and Petrology, Major element composition, Planetology, Comets and Small Bodies, Origin and evolution
Journal
Journal of Geophysical Research
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Publisher
American Geophysical Union
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