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Johnson & DePaolo 1996
Johnson, T.M. and DePaolo, D.J. (1996). Reaction-transport models for radiocarbon in groundwater: The effects of longitudinal dispersion and the use of Sr isotope ratios to correct for water-rock interaction. Water Resources Research 32: doi: 10.1029/96WR00992. issn: 0043-1397.

We expand a model for isotope ratios in groundwater-rock systems to consider the ratio of 14C to dissolved inorganic carbon, or ''percent modern carbon.'' The model couples one-dimensional advection and dispersion with water-rock interaction and radioactive decay. We use a Fickian formulation to model longitudinal macrodispersion and present a formula for the groundwater velocity error introduced when dispersion is ignored, as a function of dispersivity and decrease in percent modern carbon. For example, if the longitudinal dispersivity were one tenth the length of observation and percent modern carbon decreased tenfold along a flow path, the error would be 23%. We also present a method for inversion of 87Sr/86Sr and 14C data to obtain carbonate dissolution rates and dissolution-corrected water velocities and apply this technique using published data from the Lincolnshire aquifer, England. The results are similar to those obtained using the Δ13C method. ¿ American Geophysical Union 1996

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Abstract

Keywords
Hydrology, Groundwater hydrology, Geochemistry, Isotopic composition/chemistry, Geochemistry, Low-temperature geochemistry
Journal
Water Resources Research
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American Geophysical Union
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