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Murphy 2003
Murphy, D.M. (2003). Dehydration in cold clouds is enhanced by a transition from cubic to hexagonal ice. Geophysical Research Letters 30: doi: 10.1029/2003GL018566. issn: 0094-8276.

Cubic ice (Ic) is a metastable form of ice with very similar physical properties but different crystal symmetry than normal, hexagonal ice (Ih). Below 200 K, water preferentially nucleates to Ic, then transforms to the more stable Ih in minutes to days. As a metastable phase, Ic will necessarily have a higher vapor pressure than Ih. A cloud parcel model shows that nucleation to Ic, conversion to Ih, and the vapor pressure differential together produce larger ice crystals that can more effectively dehydrate air. The modelled effect is largest at 180 to 200 K, just the range most important for the tropical tropopause and polar stratospheric clouds. The cloud model also produces a wider size distribution when Ic is included, in agreement with observations.

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Abstract

Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Middle atmosphere--composition and chemistry
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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