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Detailed Reference Information |
Palmer, P.I., Jacob, D.J., Mickley, L.J., Blake, D.R., Sachse, G.W., Fuelberg, H.E. and Kiley, C.M. (2003). Eastern Asian emissions of anthropogenic halocarbons deduced from aircraft concentration data. Journal of Geophysical Research 108: doi: 10.1029/2003JD003591. issn: 0148-0227. |
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The Montreal Protocol restricts production of ozone-depleting halocarbons worldwide. Enforcement of the protocol has relied mainly on annual government statistics of production and consumption of these compounds (bottom-up approach). We show here that aircraft observations of halocarbon:CO enhancement ratios on regional to continental scales can be used to infer halocarbon emissions, providing independent verification of the bottom-up approach. We apply this top-down approach to aircraft observations of Asian outflow from the TRACE-P mission over the western Pacific (March--April 2001) and derive emissions from eastern Asia (China, Japan, and Korea). We derive an eastern Asian carbon tetrachloride (CCl4) source of 21.5 Gg yr-1, several-fold larger than previous estimates and amounting to ≃30% of the global budget for this gas. Our emission estimate for CFC-11 from eastern Asia is 50% higher than inventories derived from manufacturing records. Our emission estimates for methyl chloroform (CH3CCl3) and CFC-12 are in agreement with existing inventories. For halon 1211 we find only a strong local source originating from the Shanghai area. Our emission estimates for the above gases result in a ≃40% increase in the ozone depletion potential (ODP) of Asian emissions relative to previous estimates, corresponding to a ≃10% global increase in ODP. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Pollution--urban and regional, Atmospheric Composition and Structure, Troposphere--composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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