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Detailed Reference Information |
Orphal, J., Fellows, C.E. and Flaud, P.-M. (2003). The visible absorption spectrum of NO3 measured by high-resolution Fourier transform spectroscopy. Journal of Geophysical Research 108: doi: 10.1029/2002JD002489. issn: 0148-0227. |
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The visible absorption spectrum of the nitrate radical NO3 has been measured using high-resolution Fourier transform spectroscopy. The spectrum was recorded at 294 K using a resolution of 0.6 cm-1 (corresponding to 0.026 nm at 662 nm) and covers the 12600--21500 cm-1 region (465--794 nm). Compared to absorption spectra of NO3 recorded previously, the new data show improvements concerning absolute wavelength calibration (uncertainty 0.02 cm-1), and spectral resolution. A new interpretation and model of the temperature dependence of the strong (0-0) band around 662 nm are proposed. The results are important for long-path tropospheric absorption measurements of NO3 and optical remote sensing of the Earth's atmosphere from space. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Middle atmosphere--composition and chemistry, Atmospheric Composition and Structure, Troposphere--composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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