We describe a study undertaken to investigate the potential of the geotechnical centrifuge as an experimental tool to study dense nonaqueous phase liquid (DNAPL) behavior in fracture systems. Scaling laws are developed that link observations made in a centrifuge model of a fracture system to the full-scale problem (prototype). Centrifuge experiments carried out in synthetic fractures, described by smooth-walled vertical capillary tubes, demonstrate for the first time that the geotechnical centrifuge can be used to model DNAPL transport in a simplified system provided that inertial forces are negligible in both the model and the prototype. Experiments also confirm, as predicted by Kueper and McWhorter <1991>, that DNAPL invades a smooth-walled, vertical fracture when the DNAPL pool height at its entrance reaches its entry pressure. A simple mathematical model describing the displacement of the DNAPL-water interface is also presented. The predictions of this model and the experimental data are in good agreement with each other in the lower half of an invaded fracture. However, at the early stages of DNAPL invasion into the fracture, our observed DNAPL-water interface velocities are slower than predicted by the model. We attribute this to an apparent dependence of the local capillary pressure on the interface displacement velocity.