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Hynes et al. 2001
Hynes, R.G., Mössinger, J.C. and Cox, R.A. (2001). The interaction of HCl with water-ice at tropospheric temperatures. Geophysical Research Letters 28: doi: 10.1029/2000GL012706. issn: 0094-8276.

The uptake of HCl on frozen film ice surfaces was studied as a function of temperature and HCl partial pressure (PHCl) in a flow reactor. The temperatures ranged from 205 to 230 K, and PHCl was (0.4-2.0)¿10-6 Torr. The initial uptake coefficients, &ggr;, and the HCl surface coverage are reported. It was observed that the coverage varied from 3.0¿1014 molecules/cm2 at 205 K to 1.0¿1014 molecules/cm2 at 230 K. At 205 K the coverage showed no dependence on PHCl; the average surface coverage was ~(2.0¿0.7)¿1014 molecules/cm2 at saturation. This value is consistent with other studies on similarly prepared ice films. It was found that &ggr;~0.1 at 205 K, but decreased substantially when the temperature increased; however, &ggr; was insensitive to PHCl. ¿ 2001 American Geophysical Union

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Abstract

Keywords
Atmospheric Composition and Structure, Chemical kinetic and photochemical properties
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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