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Montzka et al. 2003
Montzka, S.A., Butler, J.H., Hall, B.D., Mondeel, D.J. and Elkins, J.W. (2003). A decline in tropospheric organic bromine. Geophysical Research Letters 30: doi: 10.1029/2003GL017745. issn: 0094-8276.

Recent changes in atmospheric bromine (Br) are estimated from samples collected at ten globally distributed, ground-based sites. The results indicate that the global tropospheric burden of Br from the sum of halons and methyl bromide (CH3Br) peaked in 1998 and has since declined by nearly 5% (or 0.8 ¿ 0.2 pmol mol-1 or ppt). These changes are driven primarily by a decrease of CH3Br since 1998 that is about two times larger than expected given reported declines in industrial production, a result that may suggest revisions to our understanding of the global atmospheric budget for this gas. The observations imply 25--30% larger declines in the atmospheric burden of ozone-depleting, total equivalent chlorine (ECl = Cl + Br*45) in recent years than noted previously.

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Abstract

Keywords
Atmospheric Composition and Structure, Atmospheric Composition and Structure, Middle atmosphere--composition and chemistry, Atmospheric Composition and Structure, Troposphere--composition and chemistry
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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