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Yvon-Lewis et al. 2002
Yvon-Lewis, S.A., Butler, J.H., Saltzman, E.S., Matrai, P.A., King, D.B., Tokarczyk, R., Moore, R.M. and Zhang, J. (2002). Methyl bromide cycling in a warm-core eddy of the North Atlantic Ocean. Global Biogeochemical Cycles 16: doi: 10.1029/2002GB001898. issn: 0886-6236.

We conducted a detailed investigation of the evolution of methyl bromide concentrations, degradation rates, and ventilation rates for 26 days in a naturally contained, warm-core eddy of the North Atlantic Ocean. This is the first study of the oceanic cycling of methyl bromide in a natural, contained system with a complete suite of supporting measurements of physical and chemical variables. Methyl bromide concentrations in the mixed layer ranged from 2.3 to 4.2 nmol m-3, degradation rates ranged from 0.1 to 0.9 nmol m-3 d-1, net sea-to-air exchange rates ranged from 0 to 0.5 nmol m-3 d-1, and net loss rates through the thermocline were less than 0.1 nmol m-3 d-1. From a mass balance for methyl bromide in the mixed layer, we calculated production rates ranging from <0.1 to 1.3 nmol m-3 d-1. The median of this range, 0.48 nmol m-3 d-1, is higher than the ~0.15 nmol m-3 d-1 necessary to maintain the reported global oceanic emission of 56 Gg yr-1. This is reasonable, because our study area was supersaturated in methyl bromide, whereas the ocean as a whole is undersaturated.

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Abstract

Keywords
Atmospheric Composition and Structure, Air/sea constituent fluxes (3339, 4504), Atmospheric Composition and Structure, Biosphere/atmosphere interactions, Atmospheric Composition and Structure, Constituent sources and sinks, Oceanography, Biological and Chemical, Biogeochemical cycles
Journal
Global Biogeochemical Cycles
http://www.agu.org/journals/gb/
Publisher
American Geophysical Union
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