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Renner et al. 2002
Renner, J., Evans, B. and Siddiqi, G. (2002). Dislocation creep of calcite. Journal of Geophysical Research 107: doi: 10.1029/2001JB001680. issn: 0148-0227.

When the power law equation, $dotvarepsilon$ ∝ σnexp(-Q/RT), which relates strain rate ($dotvarepsilon$), stress (σ), gas constant (R), and temperature (T), is used to describe thermally activated dislocation creep of calcite rocks, the stress sensitivity (n) and temperature sensitivity or apparent activation energy (Q) differ greatly from rock to rock. To better constrain parameters of a mechanical equation of state, we performed triaxial deformation experiments on dense synthetic aggregates of polycrystalline calcite at temperatures of 873--1073 K and strain rates between 5 ¿ 10-7 and 3 ¿ 10-3 s-1 to strains <0.20. The strength of the marbles decreases with increasing temperature or decreasing strain rate. Combining microstructure analysis with mechanical data indicates that strength decreases with increasing grain size (d) following a Hall-Petch relation. A detailed analysis of the data revealed systematic dependence of n and Q on stress, grain size, and temperature. The variations in n and Q can be accommodated by using a Peierls law, $dotvarepsilon_{P}$ = APσ2 exp(σ/σP)exp(-QP/RT). The resistance to glide, σP, is composed of an intrinsic Peierls stress and a grain size dependent back stress and is given by σP = (ΣP,0 + Kd-0.5)(Tm - T), where Tm denotes the melting temperature. The following parameters seem to apply to all calcite rocks: AP ≈ 10¿0.5 MPa-2 s-1, QP ≈ 200 kJ/mol, ΣP,0 ≈ 7.8 MPa kK-1, and K ≈ 115 MPa kK-1 ¿m0.5. Under some laboratory conditions, dislocation creep may operate simultaneously with grain size sensitive diffusion creep, complicating the quantification of the individual flow laws. More accurate flow laws will need to include the evolution of microstructure in composite flow laws, perhaps requiring a statistical description of a microstructure variable yet to be specified exactly.

BACKGROUND DATA FILES

Abstract

Keywords
Mineral Physics, Creep and deformation, Physical Properties of Rocks, Fracture and flow, Physical Properties of Rocks, Plasticity, diffusion, and creep, Tectonophysics, Rheology--crust and lithosphere
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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