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Chang & Kaufman 1977
Chang, J.S. and Kaufman, F. (1977). Upper limits of the rate constants for the reactions of CFCl3(F-11), CF2Cl2(F-12), and N2O with OH. Estimates of corresponding lower limits to their tropospheric lifetimes. Geophysical Research Letters 4: doi: 10.1029/GL004i005p00192. issn: 0094-8276.

The reactions of CFCl3, CF2Cl2, and N2O with OH are studied at temperatures up to 480 K in a discharge-flow system with resonance fluorescence detection of OH. Little, if any reaction is found, upper limits of 5,6 and 4¿10-6 cm3 s-1 are reported at 480 K for the three rate constants. The results are compared with other investigations and with reaction rate theory. On the basis of a very simple model, removal times greater than 104 years are calculated for reaction with tropospheric OH, i.e. they are negligibly slow removal processes.

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Geophysical Research Letters
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