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Detailed Reference Information |
Michel, A.E., Usher, C.R. and Grassian, V.H. (2002). Heterogeneous and catalytic uptake of ozone on mineral oxides and dusts: A Knudsen cell investigation. Geophysical Research Letters 29: doi: 10.1029/2002GL014896. issn: 0094-8276. |
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The uptake of ozone on various mineral powders has been studied using a Knudsen cell apparatus at T = 296 K. Samples included α-Al2O3, α-Fe2O3, SiO2, China loess and Saharan sand. Reactive uptake coefficients, γBET, were measured for the various particles and found to be 8 ¿ 5 ¿ 10-5 for α-Al2O3, 1.8 ¿ 0.7 ¿ 10-4 for α-Fe2O3 and 5 ¿ 3 ¿ 10-5 for SiO2. The authentic dust samples were found to have γBET values of 2.7 ¿ 0.9 ¿ 10-5 for China loess and 6 ¿ 3 ¿ 10-5 for Saharan sand. Variations in the reactivity of the Saharan sand were observed as a function of sample treatment. Under the conditions of this study, heterogeneous uptake of ozone is catalytic and results in the destruction of ozone. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Troposphere--composition and chemistry, Meteorology and Atmospheric Dynamics, Land/atmosphere interactions |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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