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Michel et al. 2002
Michel, A.E., Usher, C.R. and Grassian, V.H. (2002). Heterogeneous and catalytic uptake of ozone on mineral oxides and dusts: A Knudsen cell investigation. Geophysical Research Letters 29: doi: 10.1029/2002GL014896. issn: 0094-8276.

The uptake of ozone on various mineral powders has been studied using a Knudsen cell apparatus at T = 296 K. Samples included α-Al2O3, α-Fe2O3, SiO2, China loess and Saharan sand. Reactive uptake coefficients, γBET, were measured for the various particles and found to be 8 ¿ 5 ¿ 10-5 for α-Al2O3, 1.8 ¿ 0.7 ¿ 10-4 for α-Fe2O3 and 5 ¿ 3 ¿ 10-5 for SiO2. The authentic dust samples were found to have γBET values of 2.7 ¿ 0.9 ¿ 10-5 for China loess and 6 ¿ 3 ¿ 10-5 for Saharan sand. Variations in the reactivity of the Saharan sand were observed as a function of sample treatment. Under the conditions of this study, heterogeneous uptake of ozone is catalytic and results in the destruction of ozone.

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Abstract

Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Troposphere--composition and chemistry, Meteorology and Atmospheric Dynamics, Land/atmosphere interactions
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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