Olivine within the lowest temperature regions of subducting oceanic lithosphere may persist metastably to depths well below the equilibrium phase boundary for transformation to ¿ phase. This may produce a tapering low seismic velocity wedge within the slab in the transition zone; transformational faulting of such metastable olivine has been proposed as a possible explanation of deep earthquakes. Detecting seismic velocity structure associated with metastable olivine within a slab using seismic wave arrival time information alone has proven problematic. Motivated by previous two-dimensional numerical calculations for upgoing and downgoing seismic waves, a three-dimensional Gaussian beam method is used to assess whether the azimuthally varying teleseismic amplitude signature produced by a slab with an internal wedge of metastable olivine is distinguishable from that for a slab with equilibrium transitions. Five slab velocity structures are considered: a thermal model with horizontal phase transitions at the same depths as in ambient mantle, two models incorporating equilibrium transitions within the slab, and two models with tongues of metastable olivine. A depth- and temperature-dependent thermal conductivity term and the effect of the latent heat of transformation of olivine to ¿ phase are included in the thermal modeling. Three-dimensional dynamic ray tracing and Gaussian beam summation are performed for events located at different depths and lateral positions for each of the slab models. For sources near 400 km depth the presence of low-velocity metastable olivine produces relatively complex azimuthal shear wave amplitude patterns compared to thermal and equilibrium models. Comparison with observed amplitudes for four events in the Kurile slab indicates that allowing for internal slab velocity complexity in the transition zone provides better agreement with observations than simple thermal and equilibrium slab models. This indicates that careful modeling of teleseismic shear wave amplitude patterns may have the resolution to detect and characterize the presence of metastable olivine in deep slabs.