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Brewer et al. 2002
Brewer, P.G., Paull, C., Peltzer, E.T., Ussler, W., Rehder, G. and Friederich, G. (2002). Measurements of the fate of gas hydrates during transit through the ocean water column. Geophysical Research Letters 29: doi: 10.1029/2002GL014727. issn: 0094-8276.

We report on controlled experiments to document the fate of naturally occurring methane hydrate released from the sea floor (780 m, 4.3¿C) by remotely operated vehicle (ROV) disturbance. Images of buoyant sediment-coated solids rising (~0.24 m/s) from the debris cloud, soon revealed clear crystals of methane hydrate as surficial material sloughed off. Decomposition and visible degassing began close to the predicted phase boundary, yet pieces initially of ~0.10 m size easily survived transit to the surface ocean. Smaller pieces dissolved or dissociated before reaching the surface ocean, yet effectively transferred gas to depths where atmospheric ventilation times are short relative to methane oxidation rates.

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Abstract

Keywords
Oceanography, Biological and Chemical, Gases, Oceanography, Biological and Chemical, Carbon cycling, Geochemistry, Marine geochemistry (4835, 4850), Oceanography, General, Continental shelf processes, Global Change, Oceans
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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