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You et al. 2003
You, C., Chan, L.-H., Gieskes, J.M. and Klinkhammer, G.P. (2003). Seawater intrusion through the oceanic crust and carbonate sediment in the Equatorial Pacific: Lithium abundance and isotopic evidence. Geophysical Research Letters 30: doi: 10.1029/2003GL018412. issn: 0094-8276.

Large-scale lateral advection of seawater within the oceanic crust is thought to be the cause of low heat flow in the Equatorial Pacific. Until now supportive evidence is limited to reversals of B and δ11B, Ca, Mg, SO4-2, Sr and 87Sr/86Sr in sediment pore waters. Here we report new evidence from a detailed study of Li and its isotopes in sediment cores from ODP Sites 844 and 851. Carbonates at these sites were significantly recrystallized leading to large variations in Li and δ7Li in the sediments and associated pore waters. In addition to diagenetic effects, distinct reversals in lithium concentration and isotopic ratio toward modern seawater composition are observed in waters near the basaltic basement, lending further support to the seawater intrusion hypothesis. Three endmembers are identified in the pore waters: seawater, a diagenetically altered component, and evolved crustal fluid. The new lithium isotopic results underscore the importance of diagenetic artifacts in carbonate sediments.

BACKGROUND DATA FILES

Abstract

Keywords
Geochemistry, Isotopic composition/chemistry, Geochemistry, Low-temperature geochemistry, Geochemistry, Marine geochemistry (4835, 4850), Marine Geology and Geophysics, Heat flow (benthic) and hydrothermal processes
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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