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Detailed Reference Information |
Ma, Y., Weber, R.J., Lee, Y.-N., Orsini, D.A., Maxwell-Meier, K., Thornton, D.C., Bandy, A.R., Clarke, A.D., Blake, D.R., Sachse, G.W., Fuelberg, H.E., Kiley, C.M., Woo, J.-H., Streets, D.G. and Carmichael, G.R. (2003). Characteristics and influence of biosmoke on the fine-particle ionic composition measured in Asian outflow during the Transport and Chemical Evolution Over the Pacific (TRACE-P) experiment. Journal of Geophysical Research 108: doi: 10.1029/2002JD003128. issn: 0148-0227. |
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We investigate the sources, prevalence, and fine-particle inorganic composition of biosmoke over the western Pacific Ocean between 24 February and 10 April 2001. The analysis is based on highly time-resolved airborne measurements of gaseous and fine-particle inorganic chemical composition made during the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) experiment. At latitudes below approximately 25¿N, relatively pure biomass burning plumes of enhanced fine-particle potassium, nitrate, ammonium, light-absorbing aerosols, and CO concentrations were observed in plumes that back trajectories and satellite fire map data suggest originated from biomass burning in southeast Asia. Fine-particle water-soluble potassium (K+) is confirmed to be a unique biosmoke tracer, and its prevalence throughout the experiment indicates that approximately 20% of the TRACE-P Asian outflow plumes were influenced, to some extent, by biomass or biofuel burning emissions. At latitudes above 25¿N, highly mixed urban/industrial and biosmoke plumes, indicated by SO42- and K+, were observed in 5 out of 53 plumes. Most plumes were found in the Yellow Sea and generally were associated with much higher fine-particle loadings than plumes lacking a biosmoke influence. The air mass back trajectories of these mixed plumes generally pass through the latitude range of between 34¿ and 40¿N on the eastern China coast, a region that includes the large urban centers of Beijing and Tianjin. A lack of biomass burning emissions based on fire maps and high correlations between K+ and pollution tracers (e.g., SO42-) suggest biofuel sources. Ratios of fine-particle potassium to sulfate are used to provide an estimate of relative contributions of biosmoke emissions to the mixed Asian plumes. The ratio is highly correlated with fine-particle volume (r2 = 0.85) and predicts that for the most polluted plume encounter in TRACE-P, approximately 60% of the plume is associated with biosmoke emissions. On average, biosmoke contributes approximately 35--40% to the measured fine inorganic aerosol mass in the mixed TRACE-P plumes intercepted north of 25¿N latitude. |
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BACKGROUND DATA FILES |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Troposphere--composition and chemistry, Atmospheric Composition and Structure, Troposphere--constituent transport and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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