EarthRef.org Reference Database (ERR)
Development and Maintenance by the EarthRef.org Database Team

Detailed Reference Information
Popp et al. 2002
Popp, B.N., Westley, M.B., Toyoda, S., Miwa, T., Dore, J.E., Yoshida, N., Rust, T.M., Sansone, F.J., Russ, M.E., Ostrom, N.E. and Ostrom, P.H. (2002). Nitrogen and oxygen isotopomeric constraints on the origins and sea-to-air flux of N2O in the oligotrophic subtropical North Pacific gyre. Global Biogeochemical Cycles 16. doi: 10.1029/2001GB001806. issn: 0886-6236.

Although the oceans are a significant source of the greenhouse gas nitrous oxide (N2O) to the atmosphere, the magnitude and characteristics of this source are poorly constrained. We present here stable isotope and isotopomer (intramolecular distribution of 15N within the linear NNO molecule) results for N2O and oxygen stable isotopic data for dissolved O2 from Station ALOHA in the subtropical North Pacific gyre near Hawaii. The results indicate shallow (~100--300 m) in situ N2O production. Results of isotope mass balance models constrain the rate of N2O production and the sea-to-air flux of N2O. Results of an isotope mass balance model that takes into account the ratios of the vertical gradients in the isotopic abundances of N, O, Nα (central N) and N¿ (terminal N) of N2O and the measured gradients of N2O concentration through the thermocline indicate that shallow in situ production contributed 40% to 75% of the sea-to-air flux of N2O. This model also indicates that the net sea-to-air flux of N2O was at least 0.4 ¿mol m-2 d-1 and could be as high as 1.0 ¿mole m-2 d-1. These model results are not statistically different from the sea-to-air flux of N2O calculated using an empirical relationship between wind speed and gas transfer rate (1.1 ¿ 0.7 ¿mole m-2 d-1) derived from measured values for wind speed, temperature and the surface mixed layer concentration of N2O. These results can be used to better constrain the global N2O budget.

BACKGROUND DATA FILES

Abstract

Keywords
Oceanography, Biological and Chemical, Gases, Atmospheric Composition and Structure, Air/sea constituent fluxes (3339, 4504), Oceanography, Biological and Chemical, Stable isotopes, Information Related to Geographic Region, Pacific Ocean
Journal
Global Biogeochemical Cycles
http://www.agu.org/journals/gb/
Publisher
American Geophysical Union
2000 Florida Avenue N.W.
Washington, D.C. 20009-1277
USA
1-202-462-6900
1-202-328-0566
service@agu.org
Click to clear formClick to return to previous pageClick to submit