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Detailed Reference Information |
Corgne, A. and Wood, B.J. (2002). CaSiO3 and CaTiO3 perovskite-melt partitioning of trace elements: Implications for gross mantle differentiation. Geophysical Research Letters 29: doi: 10.1029/2001GL014398. issn: 0094-8276. |
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We report the results of CaSiO3 perovskite-melt partitioning experiments conducted at conditions relevant to the uppermost lower mantle. Partition coefficients, measured by LA-ICPMS, show that CaSiO3 perovskite has a strong affinity for REE, Y, Th and U, making CaSiO3 the most likely host for these elements in the lower mantle. Comparison with the low-pressure analogue CaTiO3 shows that large ions partition similarly into the Ca-sites of the two perovskites. Thus CaTiO3 may be used as a model to investigate the factors controlling the partitioning of many trace ions into CaSiO3. Combined fractionation of MgSiO3 and CaSiO3 perovskites during an early magma ocean has been suggested as a means of enriching the lower mantle in silica. Our results show, however, that the chondritic upper mantle ratios of refractory lithophile elements would be lost after ~17% of perovskite fractionation. A large perovskitic layer `hidden' in the lower mantle is therefore improbable. |
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Abstract |
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Keywords
Geochemistry, Composition of the mantle, Geochemistry, Trace elements, Mineralogy and Petrology, Experimental mineralogy and petrology |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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