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Rinsland et al. 2004
Rinsland, C.P., Mahieu, E., Zander, R., Goldman, A., Wood, S. and Chiou, L. (2004). Free tropospheric measurements of formic acid (HCOOH) from infrared ground-based solar absorption spectra: Retrieval approach, evidence for a seasonal cycle, and comparison with model calculations. Journal of Geophysical Research 109: doi: 10.1029/2004JD004917. issn: 0148-0227.

The seasonal variation of the free tropospheric volume mixing ratio of formic acid (HCOOH) has been derived from high-spectral-resolution solar absorption spectra recorded with the Fourier transform spectrometer in the U.S. National Solar Observatory facility on Kitt Peak (31.9¿N, 111.6¿E, 2.09 km altitude) at a typical spectral resolution of 0.005 cm-1. The spectra have been analyzed with the SFIT2 algorithm, which is based on a semiempirical application of the optimal estimation method. Absorption by HCOOH is weak in these solar spectra, but successful retrievals have been obtained with a new procedure that fits the HCOOH ν6 band Q branch at 1105 cm-1 simultaneously with a window to account for a temperature-sensitive HDO line, which overlaps the HCOOH Q branch. After retaining only the best measurements from a database extending from June 1980 to October 2002 the retrievals show a seasonal variation, with a summer maximum and a winter minimum. Average 2.09--10 km volume mixing ratios binned in 3 month intervals range from a maximum of 792 ¿ 323 parts per trillion by volume (pptv), or 10-12, in July--September to a minimum of 313 ¿ 175 pptv in October--December, with the uncertainties corresponding to statistical means from daily averages. The results are compared with previously reported measurements and model calculations.

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Abstract

Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Pollution—urban and regional, Atmospheric Composition and Structure, Troposphere—constituent transport and chemistry, Atmospheric Composition and Structure, Transmission and scattering of radiation, Global Change, Remote sensing, troposphere, atmospheric chemistry, remote sensing
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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