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Detailed Reference Information
Vervoort et al. 2004
Vervoort, J.D., Patchett, P.J., Söderlund, U. and Baker, M. (2004). Isotopic composition of Yb and the determination of Lu concentrations and Lu/Hf ratios by isotope dilution using MC-ICPMS. Geochemistry Geophysics Geosystems 5: doi: 10.1029/2004GC000721. issn: 1525-2027.

We report Yb isotopic data for the purpose of accurately correcting measurements of Lu and Lu/Hf ratios during Multicollector Inductively Coupled Plasma Mass Spectrometer (MC-ICPMS) analysis. The Yb isotopic ratios agree with recent results of Chu et al. <2002> and Amelin and Davis <2004>, when corrected for mass fractionation to the same reference values. Protocols for Lu measurement involving simultaneous subtraction of Yb interference and application of a fractionation correction based on Yb are described. It is shown that Lu concentrations and Lu/Hf ratios determined by MC-ICPMS using this methodology are more precise and potentially more accurate than results based on analysis of Lu by Thermal Ionization Mass Spectrometry (TIMS). A number of MC-ICPMS Lu-Hf isotopic analyses of standard rocks and other geological samples, previously analyzed by TIMS, are presented. These document reproducibility of Lu/Hf within 0.2%, where most discrepancies can be assigned to the unknown Lu mass fractionation during TIMS analysis.

BACKGROUND DATA FILES

Abstract

Keywords
Geochemistry, Chemical evolution, Geochemistry, Composition of the crust, Geochemistry, Isotopic composition/chemistry, Hf isotopic analysis, Lu isotopes, MC-ICPMS, Yb isotopes
Journal
Geochemistry Geophysics Geosystems
Publisher
American Geophysical Union
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