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Afe et al. 2004
Afe, O.T., Richter, A., Sierk, B., Wittrock, F. and Burrows, J.P. (2004). BrO emission from volcanoes: A survey using GOME and SCIAMACHY measurements. Geophysical Research Letters 31: doi: 10.1029/2004GL020994. issn: 0094-8276.

Volcanic eruptions are known to be a major source of SO2 and some reactive halogen species notably HCl and HF. Recent studies have however observed the presence of large amounts of BrO with tight correlation to SO2 in a volcanic plume by ground-based spectroscopic measurements. In this work, upper limits of BrO columns have been estimated for a number of volcanic eruptions observed in measurements made by two satellite instruments - the Global Ozone Monitoring Experiment (GOME), and the new SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY). The results obtained for the eruptions covered by satellite overpasses over the Etna, Nyamuragira, Popocat¿petl, and Reventador volcanoes show no correlation between enhanced volcanic SO2 during large eruptions and the corresponding BrO columns. Evidence for BrO enhancement was also not found in the vicinity of the Soufri¿re Hills volcanoes. The possible reasons for the differences between ground-based and satellite observations are considered.

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Abstract

Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Volcanic effects, Atmospheric Composition and Structure, Instruments and techniques
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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