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Cohen & Hart 2004
Cohen, A.L. and Hart, S.R. (2004). Deglacial sea surface temperatures of the western tropical Pacific: A new look at old coral. Paleoceanography 19: doi: 10.1029/2004PA001084. issn: 0883-8305.

Using Secondary Ion Mass Spectrometry (SIMS) ion microprobe techniques, we generated annual Sr/Ca cycles with subweekly resolution from chunks of Porites coral retrieved from a Tahiti barrier reef drill core (149¿W, 17¿S), representing the period 13,650 to 13,100 years B.P. The centers of pristine skeletal septa were selectively targeted with a 10 ¿m diameter ion beam spot, avoiding adjacent pore spaces occupied by secondary aragonite needles. Applying a Sr/Ca--sea surface temperature (SST) calibration equation derived from modern Tahiti Porites having the same low growth rate as the fossil specimens, we obtained SSTs ~0.5¿--1.5¿C cooler during the B¿lling-Allerod relative to the present day, with no significant change in seasonality. On the contrary, we estimate that analysis of bulk samples would yield excessively cool Sr/Ca-based SST estimates due to the occupation by secondary aragonite crystals of up to 50% of the skeletal pore space in the ancient samples. We find that growth rate effects on coral Sr/Ca further depress the apparent mean annual derived SSTs (by >3¿C) and amplify the apparent seasonality by selectively enhancing wintertime cooling. Our microscale analysis of pristine skeleton and application of an appropriate growth-dependent calibration yield Sr/Ca-derived SSTs that are in good agreement with those derived from Mg/Ca ratios of calcitic foraminifera which indicate a continuous postglacial warming of the western tropical Pacific, in phase with the warming of the tropical Atlantic.

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Abstract

Keywords
Oceanography, General, Paleoceanography, Oceanography, General, Instruments and techniques, Oceanography, Biological and Chemical, Trace elements, tropical Pacific, sea surface temperature, Bølling-Allerod, coral Sr/Ca, ion microprobe, diagenesis
Journal
Paleoceanography
Publisher
American Geophysical Union
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