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Greaves et al. 2005
Greaves, M., Barker, S., Daunt, C. and Elderfield, H. (2005). Accuracy, standardization, and interlaboratory calibration standards for foraminiferal Mg/Ca thermometry. Geochemistry Geophysics Geosystems 6: doi: 10.1029/2004GC000790. issn: 1525-2027.

The use of liquid and solid standards for foraminiferal Mg/Ca and Sr/Ca determinations and interlaboratory calibration has been investigated. Preparation of single element standard solutions from primary solid standard material enables the preparation of mixed standard solutions with Mg/Ca and Sr/Ca ratios of known accuracy to better than 0.1%. We also investigated commercial reference materials to determine whether existing carbonate standards could be used as reference material for Mg/Ca determinations in foraminiferal calcite. We propose that, in the absence of a pure calcium carbonate standard certified for Mg/Ca, ECRM 752-1, a limestone CRM containing Mg/Ca within the range of typical foraminifera, is a suitable solid standard for interlaboratory calibration. Replicate Mg/Ca determinations showed that, provided silicate phases are removed by centrifugation, this material is homogenous within the precision of daily instrumental Mg/Ca determinations over a range of sample weights from 10 to 1000 mg, taken from two separate bottles of ECRM 752-1. Results gave an average value of Mg/Ca = 3.75 mmol/mol (0.015 s.d., 0.41% r.s.d.) on 118 determinations from the two bottles.

BACKGROUND DATA FILES

Abstract

Keywords
Oceanography, Biological and Chemical, Geochemistry, Oceanography, Biological and Chemical, Trace elements, Paleoceanography, Geochemical tracers, Paleoceanography, Instruments and techniques, calibration standards, carbonates, Mg/Ca thermometry, reference materials
Journal
Geochemistry Geophysics Geosystems
Publisher
American Geophysical Union
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