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Gangstø et al. 2005
Gangstø, R., Haugan, P.M. and Alendal, G. (2005). Parameterization of drag and dissolution of rising CO2 drops in seawater. Geophysical Research Letters 32: doi: 10.1029/2005GL022637. issn: 0094-8276.

In this work the dynamics and dissolution of a hydrate-covered CO2 drop were studied, using a numeric model and data from one of very few CO2 experiments performed in the real ocean. A theory including the standard drag curve of rigid spheres was shown not to fit the observed drop rise velocity. However, a drag parameterization supported by numerous laboratory experiments with gas bubbles provides a good match of the observed rise velocity of a liquid CO2 drop covered with hydrate. The results confirm laboratory results showing that shape is a key factor determining the CO2 drop dynamics. We also found that hydrate reduces the mass transfer of the observed drop by a factor of 2, which is compatible with laboratory experiments. Numerical experiments with different drop sizes showed that the choice of drag parameterization has a significant impact on the estimated vertical distribution of dissolved CO2.

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Abstract

Keywords
Oceanography, General, Numerical modeling (0545, 0560), Oceanography, Physical, Turbulence, diffusion, and mixing processes, Oceanography, Biological and Chemical, Carbon cycling
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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