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Tanhua & Wallace 2005
Tanhua, T. and Wallace, D.W.R. (2005). Consistency of TTO-NAS inorganic carbon data with modern measurements. Geophysical Research Letters 32: doi: 10.1029/2005GL023248. issn: 0094-8276.

We compare alkalinity and total dissolved inorganic carbon (DIC) measurements made during the Transient Tracers in the Ocean, North Atlantic Study (TTO-NAS) in 1981 with modern measurements from a TTO reoccupation cruise in 2004 (M60/5). We find that the TTO-NAS alkalinity values are 3.6 ¿ 2.3 ¿mol kg-1 higher than modern alkalinity data tied to Certified Reference Materials. The TTO-NAS DIC values re-calculated from original alkalinity and discrete-pCO2 data using currently accepted constants are 3.8 ¿mol kg-1 higher than those reported in the revised TTO data set. This difference is reduced to 0.7 ¿mol kg-1 when our suggested correction to the TTO-NAS alkalinity is applied. These re-calculated DIC values are 2.4 ¿mol kg-1 too low relative to contemporaneous measurements made by the vacuum extraction/manometric Certified method. Application of this correction brings the TTO data into almost perfect agreement with modern measurements for slowly-ventilated deep water of the eastern Atlantic.

BACKGROUND DATA FILES

Abstract

Keywords
Oceanography, General, Time series experiments (1872, 3270, 4475), Oceanography, Biological and Chemical, Marine inorganic chemistry, Oceanography, Biological and Chemical, Carbon cycling
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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