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Detailed Reference Information |
Tanhua, T. and Wallace, D.W.R. (2005). Consistency of TTO-NAS inorganic carbon data with modern measurements. Geophysical Research Letters 32: doi: 10.1029/2005GL023248. issn: 0094-8276. |
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We compare alkalinity and total dissolved inorganic carbon (DIC) measurements made during the Transient Tracers in the Ocean, North Atlantic Study (TTO-NAS) in 1981 with modern measurements from a TTO reoccupation cruise in 2004 (M60/5). We find that the TTO-NAS alkalinity values are 3.6 ¿ 2.3 ¿mol kg-1 higher than modern alkalinity data tied to Certified Reference Materials. The TTO-NAS DIC values re-calculated from original alkalinity and discrete-pCO2 data using currently accepted constants are 3.8 ¿mol kg-1 higher than those reported in the revised TTO data set. This difference is reduced to 0.7 ¿mol kg-1 when our suggested correction to the TTO-NAS alkalinity is applied. These re-calculated DIC values are 2.4 ¿mol kg-1 too low relative to contemporaneous measurements made by the vacuum extraction/manometric Certified method. Application of this correction brings the TTO data into almost perfect agreement with modern measurements for slowly-ventilated deep water of the eastern Atlantic. |
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BACKGROUND DATA FILES |
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Abstract |
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Keywords
Oceanography, General, Time series experiments (1872, 3270, 4475), Oceanography, Biological and Chemical, Marine inorganic chemistry, Oceanography, Biological and Chemical, Carbon cycling |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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