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Detailed Reference Information |
Sørensen, L.L., Pryor, S.C., de Leeuw, G. and Schulz, M. (2005). Flux divergence of nitric acid in the marine atmospheric surface layer. Journal of Geophysical Research 110: doi: 10.1029/2004JD005403. issn: 0148-0227. |
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It is hypothesized that removal of HNO3 from the atmosphere close to the sea surface is due to two processes: dry deposition to the sea surface and chemical reaction with sea spray. The latter process invalidates the application of the constant flux layer assumption to calculate dry deposition based on concentrations of HNO3 at, e.g., a reference height of 10 m. A field experiment was carried out to investigate this hypothesis, and the measured concentration profiles were found to differ dramatically from the log linear profiles, which would have been produced by turbulent transport only. Surface fluxes of HNO3 were calculated from the measured profiles taking chemical reactions into account and were compared to surface fluxes calculated by the traditional resistance method. It was found that the surface fluxes could be a factor of two less when chemical reactions are taken into account, depending on the characteristics of the near-surface aerosols. HNO3 loss rates due to heterogeneous chemistry are calculated by two independent methods and are compared. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801, 4906), Atmospheric Composition and Structure, Air/sea constituent fluxes (3339, 4504), Atmospheric Processes, Ocean/atmosphere interactions (0312, 4504), sea spray, deposition, air-sea exchange, nitrogen, atmospheric reactions |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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