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Detailed Reference Information |
Wehner, B., Petäjä, T., Boy, M., Engler, C., Birmili, W., Tuch, T., Wiedensohler, A. and Kulmala, M. (2005). The contribution of sulfuric acid and non-volatile compounds on the growth of freshly formed atmospheric aerosols. Geophysical Research Letters 32: doi: 10.1029/2005GL023827. issn: 0094-8276. |
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The formation of atmospheric aerosol particles (homogeneous nucleation, forming of stable clusters ~1 nm in size), their subsequent growth to detectable sizes (>3 nm), and to the size of cloud condensation nuclei, remains one of the least understood atmospheric processes upon which global climate change critically depends. However, a quantitative model explanation for the growth of freshly formed aerosols has been missing. In this study, we present observations explaining the nucleation mode (3--25 nm) growth. Aerosol particles typically grow from 3 nm to 60--70 nm during a day, while their non-volatile cores grow by 10--20 nm as well. The total particle growth rate is 2--8 nm/h while the non-volatile core material can explain 20--40%. According to our results, sulfuric acid can explain the remainder of the growth, until the particle diameter is around 10--20 nm. After that secondary organic compounds significantly take part in growth process. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801, 4906), Atmospheric Composition and Structure, Troposphere, composition and chemistry, Global Change, Atmosphere (0315, 0325) |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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