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Detailed Reference Information |
Wingenter, O.W., Sive, B.C., Blake, N.J., Blake, D.R. and Rowland, F.S. (2005). Atomic chlorine concentrations derived from ethane and hydroxyl measurements over the equatorial Pacific Ocean: Implication for dimethyl sulfide and bromine monoxide. Journal of Geophysical Research 110. doi: 10.1029/2005JD005875. issn: 0148-0227. |
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Atomic chlorine and bromine monoxide concentrations ( and ) and dimethyl sulfide (DMS) sea-air fluxes are estimated from data collected during a Lagrangian flight made near Christmas Island (2¿N, 157¿W) during August 1996 aboard the NASA P3-B aircraft. Intensive hydrocarbon sampling began in the surface layer (SL) one-half hour after sunrise and continued until ~1300 local solar time. Our empirical model includes in situ observations of hydroxyl and precise measurements of ethane (C2H6) mixing ratios. Ethane was ~40 pptv higher in the buffer layer (BuL) than in the SL, thus vertical exchange tended to replace any C2H6 that was photochemically removed in the SL. In spite of this, SL C2H6 mixing ratios decreased significantly during the flight. Using only the measured and estimated vertical mixing, our mass balance equation cannot explain all of the observed SL C2H6 loss. However, when an initial of 8.4 (¿2.0) ¿ 104 Cl cm-3, decreasing to 5.7 (¿2.0) ¿ 104 Cl cm-3 at midday, is included, the observed and estimated C2H6 values are in excellent agreement. Using our , we estimate a DMS flux a factor of 2 higher than when HO is the only oxidant considered. This flux estimate, when compared to that derived by Lenschow et al. (1999), suggests that if the differences are real, we may be missing a loss term. Best agreement occurs when an average BrO mixing ratio of 1.3 (¿1.3) pptv is included in our mass balance equation. |
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BACKGROUND DATA FILES |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Air/sea constituent fluxes (3339, 4504), Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801, 4906), Atmospheric Composition and Structure, Geochemical cycles |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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