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Detailed Reference Information
Canty et al. 2006
Canty, T., Pickett, H.M., Salawitch, R.J., Jucks, K.W., Traub, W.A. and Waters, J.W. (2006). Stratospheric and mesospheric HOx: Results from Aura MLS and FIRS-2. Geophysical Research Letters 33: doi: 10.1029/2006GL025964. issn: 0094-8276.

Observations of OH and HO2 from Aura MLS for four seasons and diurnal profiles from the FIRS-2 balloon instrument for Fall 2004 are compared with photochemical model simulations testing three sets of kinetics parameters. MLS and FIRS-2 OH profiles, between 25--60 km, are lower than model results using standard kinetics. Use of a faster, previously published rate constant for O+OH leads to better agreement with MLS and FIRS-2 profiles of OH. A 20% increase in the rate of HO2+OH and the faster rate for O+OH results in improved overall agreement with observations of OH, HO2, HOx, and HO2/OH. Since the MLS and FIRS-2 observations of HOx are reasonably well described by these models, they are therefore not consistent with the previously reported HOx dilemma. However, all models considered here result in calculated odd oxygen loss exceeding production, consistent with the long standing ozone deficit problem.

BACKGROUND DATA FILES

Abstract

Keywords
Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Middle atmosphere, composition and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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