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Livesey et al. 2006
Livesey, N.J., Kovalenko, L.J., Salawitch, R.J., MacKenzie, I.A., Chipperfield, M.P., Read, W.G., Jarnot, R.F. and Waters, J.W. (2006). EOS Microwave Limb Sounder observations of upper stratospheric BrO: Implications for total bromine. Geophysical Research Letters 33: doi: 10.1029/2006GL026930. issn: 0094-8276.

This paper describes new total stratospheric inorganic bromine (Bry) abundance estimates inferred from the first global observations of upper stratospheric BrO, made by the EOS Microwave Limb Sounder on the Aura satellite. Our 'best estimate' of total upper stratospheric bromine loading (based on JPL-2002 kinetics with the addition of a BrONO2 + O reaction) is 18.6 ¿ 5.5 pptv, for the period September 2004 to August 2005, from 55¿ S to 55¿ N. This implies a contribution of 3.0 ¿ 5.5 pptv from sources other than long lived CH3Br and halons. The possibility of such other sources has been raised by balloon, aircraft and satellite observations of BrO in the lower and middle stratosphere. These upper stratospheric observations provide new information to help resolve the current uncertainty in stratospheric bromine loading. The abundance of bromine, particularly in the lower stratosphere, is a significant factor in the budget of stratospheric O3.

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere, composition and chemistry, Atmospheric Composition and Structure, Instruments and techniques, Atmospheric Composition and Structure, Constituent sources and sinks
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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