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Detailed Reference Information |
Barroux, G., Sonke, J.E., Boaventura, G., Viers, J., Godderis, Y., Bonnet, M., Sondag, F., Gardoll, S., Lagane, C. and Seyler, P. (2006). Seasonal dissolved rare earth element dynamics of the Amazon River main stem, its tributaries, and the Curuaí floodplain. Geochemistry Geophysics Geosystems 7: doi: 10.1029/2006GC001244. issn: 1525-2027. |
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We present a comprehensive dissolved rare earth element (REE) data set for the Amazon River and its main tributaries, Rio Negro, Solim¿es, and Madeira, as well as the Curua¿ floodplain. The two-year time series show that REE vary seasonally with discharge in each of the tributaries, and indicate a hydrologically dominated control. Upper crust normalized REE patterns are relatively constant throughout the year, with Ce/Ce* anomalies being positively related to discharge. We propose revised annual dissolved REE fluxes to the surface Atlantic Ocean based on an integration of the seasonal data. For Nd (<0.22 ¿m) this results in an average flux of 607 ¿ 43 T/yr, which is at least 1.6 times larger than the previous estimate of 374 T/yr (<0.45 ¿m) based on low water stage data. Moreover, during the high water season the maximum Nd flux measures 1277 t.yr-1, constituting 30% of the required flux to the Atlantic Ocean (Tachikawa et al., 2003). Consequently, a smaller contribution of Nd from atmospheric and river particle desorption is required than was previously suggested. A mass balance of Amazon tributaries and observed fluxes at ¿bidos indicates that dissolved LREE behave quasi-conservatively. Conversely, the HREE mass balance presents a deficit during the high water stages, which could be related to the passage of water through the floodplain system accompanied by solid/dissolved phase transfer. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Geochemical cycles, Geochemistry, Composition of the hydrosphere, Geochemistry, Major and trace element geochemistry |
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Journal
Geochemistry Geophysics Geosystems |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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