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Berquó et al. 2007
Berquó, T.S., Banerjee, S.K., Ford, R.G., Penn, R.L. and Pichler, T. (2007). High crystallinity Si-ferrihydrite: An insight into its Néel temperature and size dependence of magnetic properties. Journal of Geophysical Research 112: doi: 10.1029/2006JB004583. issn: 0148-0227.

Ferrihydrite, an antiferromagnetic iron oxyhydroxide with resulting magnetization due to uncompensated spins, is of great importance for the cycling of many trace metals in the environment. Four ferrihydrite samples prepared with 1.3 to 3.5 wt% of Si at different synthesis temperatures (7.50C, 220C, 500C, and 750C) were studied by temperature-dependent hysteresis loops, ZFC/FC susceptibility curves, ac susceptibility and Mvssbauer spectroscopy. The incorporation of Si into the ferrihydrite during synthesis changed the properties of this mineral. Interestingly, seven sharp lines were observed in the X-ray diffraction pattern of the ferrihydrite samples prepared at 500C and 750C. In general, both XRD and magnetism demonstrate that particle size decreased (from 23 nm to 2 nm) and particle size distribution narrowed as the synthesis temperature was lowered. Those samples prepared between 7.50C and 500C showed the expected superparamagnetic behavior of ferrihydrite below 300 K. The ferrihydrite prepared at 750C was unusually coarse-grained and had a blocking temperature above 300 K. Extrapolation of induced magnetization from the largest particles with the highest crystallinity allowed an estimate of a ferrihydrite Niel temperature of around 422 K. We also present XRD and magnetic data from large natural Si-ferrihydrite collected from a marine shallow-water hydrothermal area that formed at a temperature of approximately 880C.

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Keywords
Geomagnetism and Paleomagnetism, Rock and mineral magnetism, Geomagnetism and Paleomagnetism, Magnetic mineralogy and petrology, Geomagnetism and Paleomagnetism, Environmental magnetism
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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