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Butz et al. 2007
Butz, A., Bösch, H., Camy-Peyret, C., Dorf, M., Engel, A., Payan, S. and Pfeilsticker, K. (2007). Observational constraints on the kinetics of the ClO-BrO and ClO-ClO ozone loss cycles in the Arctic winter stratosphere. Geophysical Research Letters 34: doi: 10.1029/2006GL028718. issn: 0094-8276.

Observations of the balloon-borne LPMA/DOAS remote sensing instruments performed in the Arctic stratosphere in February 1999 are used to constrain a photochemical model. Measurements of all relevant nitrogen, chlorine, and bromine species indicate that moderate heterogeneous chlorine activation occurred in a filament of the Arctic vortex. Model-measurement comparisons for OClO serve as an indicator of how well various scenarios of the involved reaction kinetics, in particular of the ClO-BrO and the ClO-ClO cycles, reproduce the observations. Recent suggestions for the photolysis rate of the ClO dimer, the equilibrium constant between ClO dimer and monomer, the rate of the ClO-ClO association reaction, and the branching ratio of the ClO-BrO reaction are consistent with the observations. Formation of an unstable isomer of ClONO2 cannot be reconciled with the observations. Modeled odd oxygen loss rates can be larger by 10% to 20% for the updated reaction kinetics compared to standard recommendations.

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere, composition and chemistry, Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Processes, Remote sensing
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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