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Arnold et al. 1992
Arnold, F., Petzoldt, K. and Reimer, E. (1992). On the formation and sedimentation of stratospheric nitric acid aerosols: Implications for polar ozone destruction. Geophysical Research Letters 19: doi: 10.1029/92GL00652. issn: 0094-8276.

The formation and sedimentation of nitric acid-aerosols (NA-aerosols) in the winter polar stratosphere is investigated in the light of recent mass spectrometric in-situ measurements of gaseous nitric acid performed in the winter arctic stratosphere. We revisit the nitric acid measurements and extend their interpretation by carrying out isentropic trajectory calculations of the airmasses encountered in these experiments and by considering aerosol measurements, which became available recently. Our analysis shows that the mass spectrometer measurements provide strong evidence for nitric acid due to sedimentation of HNO3-containing aerosols. Both these processes promote halogen-catalysed destruction of ozone. Moreover, it is concluded that nitric acid nucleation is less efficient than expected from simple equilibrium considerations. Probably, this is due to rapid cooling and inefficient nucleation (inefficient activation of preexisting H2SO4/H2O-aerosols for HNO3/H2O-condensation) allowing only a small fraction of the preexisting H2SO4/H2O-aerosols to serve as active nuclei. ¿ American Geophysical Union 1992 ¿ American Geophysical Union 1992

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles, Atmospheric Composition and Structure, Cloud physics and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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