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Detailed Reference Information |
Anthony, S.E., Tisdale, R.T., Disselkamp, R.S., Tolbert, M.A. and Wilson, J.C. (1995). FTIR studies of low temperature sulfuric acid aerosols. Geophysical Research Letters 22: doi: 10.1029/95GL01031. issn: 0094-8276. |
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Fourier transform infrared (FTIR) spectroscopy was used to study low temperature sulfuric acid aerosols representative of global stratospheric sulfate aerosols (SSAs). Sub-micrometer sized sulfuric acid (H2SO4) particles were generated using a constant output atomizer source. The particles were then exposed to water vapor before being injected into a low temperature cell. Multipass transmission FTIR spectroscopy was used to determine the phase and composition of the aerosols as a function of time for periods of up to 5 hours. Binary H2SO4/H2O aerosols with compositions from 35 to 95 wt % H2SO4 remained liquid for over 3 hours at temperatures ranging from 189--240 K. These results suggest that it is very difficult to freeze SSAs via homogeneous nucleation. Attempts to form aerosols more dilute than 35 wt % H2SO4 resulted in ice formation. ¿ American Geophysical Union 1995 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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